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Educate Me! How to I protect my toners from changing color?

How do I protect my toners from changing color? I just went viewed some of my PCGS slabbed coins stored in the blue boxes and I noticed 2 have changed colors. One overall and the other started dark a small area of black toning at the rim? Any suggestions and advice will be appreciated.

I would like to keep these and my others are they are.

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    gecko109gecko109 Posts: 8,231
    Intercept sheild.
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    savoyspecialsavoyspecial Posts: 7,366 ✭✭✭✭
    intercept shields should retard the progression

    www.brunkauctions.com

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    TwoSides2aCoinTwoSides2aCoin Posts: 45,038 ✭✭✭✭✭
    If you remember that metal is reactive, you should sleep a lot better.
    Toners are that for a reason. It will continue long after we are dead.
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    TwoSides2aCoinTwoSides2aCoin Posts: 45,038 ✭✭✭✭✭
    Let them babies grow image Don't prevent it , let it happen in all it's splendor !
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    gecko109gecko109 Posts: 8,231


    << <i>If you remember that metal is reactive, you should sleep a lot better.
    Toners are that for a reason. It will continue long after we are dead. >>




    Not if placed in an intercept sheild for slabs. There is a "sacrificial" metal (copper I think) that will absorb any substances that might have otherwise attacked a coin in this protective holder. Its quite a good concept actually. However, since no long term data on these is yet available, I dont know how often the box should be changed. But I'd imagine no more frequently than every 5 years or so, depending on the environment the coin is stored in of course.
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    TwoSides2aCoinTwoSides2aCoin Posts: 45,038 ✭✭✭✭✭
    Phil,
    I will not argue the intercept shield benefit as a preventative measure in "KEEPING" something the way it is. I'm just sayin' image From the way the coin is thinking. We can be proactive, but it's gonna do what it does.
    We'll see, in time.
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    MikeInFLMikeInFL Posts: 10,192 ✭✭✭✭


    << <i>How do I protect my toners from changing color? I just went viewed some of my PCGS slabbed coins stored in the blue boxes and I noticed 2 have changed colors. One overall and the other started dark a small area of black toning at the rim? Any suggestions and advice will be appreciated. >>



    I would store them in a place that has a stable temperature with an ample amount of silica dessicant (to limit the humidity). IS products may help as well, but as others have said, there is limited information on their long-term efficacy.
    Collector of Large Cents, US Type, and modern pocket change.
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    The notion that a toned coin will continue to tone is not entirely accurate. If there are no contaminants on the coins surface and the coin has been removed from the original environment that perpetuated the toning (bag, album, roll) then in most cases the toning will stop or virtually stop. It may take many decades or centuries for that mater for any noticable diffence in toning to appear. If toned coin is stored in the absence of contaminants like sulfer then you should not expect to see any real changes. Obviously TPG Holder are not air tight so storing your slabbed coins in a controled environment is still critical but you may have a more serious issue like active contaminants still on the coins surface.

    How long have the coins been in storage? Another concern is that AT coins are notorious for changing color over time so while the color change doesn't automatically make your coins AT.....it could be a red flag that something may have been applied to the coins surface sometime in the past and whatever was applied coould continue to degrade the colors in toning until it goes black.

    image
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    habaracahabaraca Posts: 2,106 ✭✭✭✭✭
    crack them out dip them in coin dipper then
    dip them in clear plastic or spray with clear plastic spray
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    BECOKABECOKA Posts: 16,961 ✭✭✭
    Use a vegetable sealer.

    If you seal them in plastic and suck all the air out with the sealer then there is nothing to allow continuation of the color change.
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    << <i>Use a vegetable sealer.

    If you seal them in plastic and suck all the air out with the sealer then there is nothing to allow continuation of the color change. >>




    Plus they still taste great years later.......

    image


    Maybe I am thinking of the little chocolate gold ones image
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    BcsicanBcsican Posts: 1,068
    I have a 59 Proof Franklin that went into the holder cameo

    ten years ago, it has been changing color for those ten years,

    The frost is now limited to just the top of Franklins head, the rest

    of his head and face are covered in a purple haze, not ulgy but

    I have been surprised it just keeps toning growing each year

    more purple in color...when I bought it there was not a speck of color just white cameo...

    now most the whole face is covered....
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    tahoe98tahoe98 Posts: 11,388 ✭✭✭


    .........i don't think you can stop it, even if you poured molten glass over them! i think once it's ON the metal, it's just a matter of time before it advances, slowly yes, but will still "ripen" towards decay.image
    "government is not reason, it is not eloquence-it is a force! like fire, it is a dangerous servant and a fearful master; never for a moment should it be left to irresponsible action." George Washington
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    Thanks everyone, great advice and a number of options.
    Missing My Life -PSA-Please Watch- 30 seconds could help someone you know

    "If I say something in the woods, and my wife isn't around to hear it. Am I still wrong?"
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    << <i>Use a vegetable sealer.

    If you seal them in plastic and suck all the air out with the sealer then there is nothing to allow continuation of the color change. >>



    Yes that is what I was going to say. I have a few dozen Monster Morgans sealed like that.
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    PerryHallPerryHall Posts: 47,540 ✭✭✭✭✭
    Wrap them tightly in Taco Bell napkins.image

    Worry is the interest you pay on a debt you may not owe.
    "Paper money eventually returns to its intrinsic value---zero."----Voltaire
    "Everything you say should be true, but not everything true should be said."----Voltaire

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    AnkurJAnkurJ Posts: 11,375 ✭✭✭✭
    Send them to me, I will take excellent care of them image
    All coins kept in bank vaults.
    PCGS Registries
    Box of 20
    SeaEagleCoins: 11/14/54-4/5/12. Miss you Larry!
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    gecko109gecko109 Posts: 8,231


    << <i>.........i don't think you can stop it, even if you poured molten glass over them! i think once it's ON the metal, it's just a matter of time before it advances, slowly yes, but will still "ripen" towards decay.image >>




    Im not a chemistry major, but if I had to wager a guess, i'd say that oxygen is an extremely important catalyst for any type of OXIDATION. Remove the oxygen, remove further oxidation.
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    << <i>Im not a chemistry major, but if I had to wager a guess, i'd say that oxygen is an extremely important catalyst for any type of OXIDATION. Remove the oxygen, remove further oxidation.
    >>



    It works with rust on a car.
    Missing My Life -PSA-Please Watch- 30 seconds could help someone you know

    "If I say something in the woods, and my wife isn't around to hear it. Am I still wrong?"
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    i know how but it involves breaking them out of the slabs which i`m sure you don`t want to hear.
    my ebay items BST transactions/swaps/giveaways with: Tiny, raycyca,mrpaseo, Dollar2007,Whatafind, Boom, packers88, DBSTrader2, 19Lyds, Mar327, pontiacinf, ElmerFusterpuck.
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    COALPORTERCOALPORTER Posts: 2,900 ✭✭
    I guess your coins are AT. True toned (oxidized or sulfide) coins form a ceramic coating, which cannot further react unless the metal is somehow exposed by removing this ceramic layer.

    (oxidized metal is no longer a metal- it's a ceramic.)
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    COALPORTERCOALPORTER Posts: 2,900 ✭✭


    << <i>Use a vegetable sealer.

    If you seal them in plastic and suck all the air out with the sealer then there is nothing to allow continuation of the color change. >>




    do those bags have PVC ?
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    crazyhounddogcrazyhounddog Posts: 14,215 ✭✭✭✭✭
    We won't know the answer to this question for about a hundred years.image
    The bitterness of "Poor Quality" is remembered long after the sweetness of low price is forgotten.
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    BearBear Posts: 18,953 ✭✭✭
    I have stored my slabbed coins in the blue PCGS Box

    in the bank vault for over 5 years with no change in

    color. Heat and humidity can be a problem as well as

    contaminants that may remain on coin surfaces after

    slabbing. Finally, coin doctoring may have occured to coin

    before slabbing which would tend to cause deterioration to

    the surfaces over time.
    There once was a place called
    Camelotimage
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    << <i>I have stored my slabbed coins in the blue PCGS Box

    in the bank vault for over 5 years with no change in

    color. Heat and humidity can be a problem as well as

    contaminants that may remain on coin surfaces after

    slabbing. Finally, coin doctoring may have occured to coin

    before slabbing which would tend to cause deterioration to

    the surfaces over time. >>



    A very good summary of what I was eluding too....I am sure I have a jelly donut around here somewhere for you Bear image
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    Very interesting topic. I have wondered about this myself. Thanks to all who responed with info to this board.
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    On the opposite side of this discussion....I took a silver quarter and AT'd it using matches and a heat lamp and it came out with amazing colors, purples, orange, blues etc....very vivid and attractive colors but clearly AT. That was 3 years ago and now the coin is very dark and most of the colors are subdued so even though I did not spray chemicals on the surface...the surface contaminants and the unstable nature of AT's coins has created a great experiment of what can happen if you purchase bad coins and have them continue to tone. To date I have never had a toned coin in a NGC or PCGS holder turn....or darken even though I know there are some AT coins in top holders.
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    YaHaYaHa Posts: 4,220
    Move to Canada and go to your music store once a month for a check up.image
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    keetskeets Posts: 25,351 ✭✭✭✭✭
    i didn't read the entire list of replies, so please excuse me if i repeat something.

    two points come to mind:
    1. coins will always continue to tone. not true
    2. Intercept Shield products will protect your coins. not true

    there are really two things to consider with the OP's question of How to(do) I protect my toners from changing color? the first that comes to mind is that if the coins are changing color there must be a contaminant on the coin inside of the capsule and the second is an unstable storage environment. if there is a contaminant on the coin then the Intercept Shield products can't nuetralize it and the unstable environment wherever the coins are stored will cause the toning to continue.

    the only recourse i see is to crack the coins out of the holders, rinse them with acetone to remove the contamination and then store in a stable environment with/without the Intercept Shield.
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    << <i>I guess your coins are AT >>



    How could that be, they are slabbed image

    The coins pictured are not turning, I want to protect them. All coins were stored in a safty deposit box, but not all the time, I do take them out to look at them. After all Thats why I bought them. I have a few others that did start changing . I may just end up selling anything that starts to change in a way I am not happy about.

    I am interested in learning more about the vacuum sealing. I'll have to see what I can find out. Possibly seal a whole bue box with the slabbed coins inside.

    Thanks again and keep the ideas coming...




    Missing My Life -PSA-Please Watch- 30 seconds could help someone you know

    "If I say something in the woods, and my wife isn't around to hear it. Am I still wrong?"
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    sinin1sinin1 Posts: 7,500
    air and light accelerate any reactions

    (and heat and moisture)


    wrap your slabs a couple times in aluminum foil
    and keep in cooler place


    remember slabs by themselves are not airtight (or moisture tight)
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    << <i>

    << <i>I guess your coins are AT >>



    How could that be, they are slabbed image

    >>




    I don't believe the coins you have pictured are AT....not sure what the original poster was inferring but.....

    Please keep in mind that there are thousands of Artificially toned coins in top tier slabs in the marketplace today. The coin doctors are very good at what they do and it's not suprising that they get some of their creations into slabs. Education is your best defense when buying coins raw or slabbed. By going to shows or searching auction archives like those at Heritage you can get a really good idea of how certain coin series tone, typical colors and patterns etc. Then when you see say a Peace dollar with rainbow bands of toning like you typically find on Morgans you will automatically question the color. It doesn't automatically mean the coin is AT but it will at least send off a warning siren in your head that certain series and denominations have very specific toning patterns and color progressions based on typical storage methods, planchet preparation and strike characteristics. Do not take a geniue NGC or PCGS holder at face value and believe you are fully protected....buy the coin and not the slab. image
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    dorkkarldorkkarl Posts: 12,691 ✭✭✭
    remove from the slabs, put in airtight mylar holders. it's really the only practical way to basically guarantee inert storage

    plastic exudes chemicals, no matter what a slab co. tells you

    K S
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    AnkurJAnkurJ Posts: 11,375 ✭✭✭✭
    If the coins were NT, I do beleive that Intercept Shield double boxes will protect them from continued toning. I have a bunch of toned morgans and other toned type in those boxes for about 3 years now, and none of them have changed.

    AJ
    All coins kept in bank vaults.
    PCGS Registries
    Box of 20
    SeaEagleCoins: 11/14/54-4/5/12. Miss you Larry!
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    ToneloverTonelover Posts: 1,554
    I believe that the usefulness of Intercept Shield boxes is very debatable.

    It is my understanding that a truly original toned coin once removed from its toning source and slabbed would prove to remain quite stable going forward and does not really require specific care to keep it from toning more. Yes, environmental conditions such as humidity can affect that to an extent, particularly in the case of red copper turning to red brown, etc but silver coins in particular are very stable once encapsulated. There are other exceptions such as Silver Eagles which due to their purity are much more reactive, develop milk spots or even get toned by the vapors from the plastic in the slab itself but. But my comments apply to normal 90% silver for the most part.

    I have had only one coin out of about two hundred which changed color significantly during my time of ownership and I honestly feel that it was questionable to begin with. But anything I own which has typical mint set, envelope or album color, or even what I believe to be original white when originally purchased has not changed one iota in as much as 8 years. And they have been stored of all extremes of temperature and humidity from California to New Hampshire. I have had coins tone in albums in a matter of a couple years but as far as slabbed coins go, I don't lose a wink of sleep about having to protect them further.

    Many people don't realize that the main reason for coins toning in a slab, particularly in rapid fashion is because it was tampered with, dipped, acetoned, etc, artificially colored, etc. prior to being holdered and the surfaces still have contaminants on them which are still reacting with the surfaces. That is probably 90%+ of the cause for coins toning in a holder so rather than worry about Intercept Shield holders and vacuum bags and what not, try to worry more about whether a coin has been played with. I know it is easier said than done to pick them with 100% certainty but you might as well be focusing your attention in the right direction.



    << <i>If the coins were NT, I do beleive that Intercept Shield double boxes will protect them from continued toning. I have a bunch of toned morgans and other toned type in those boxes for about 3 years now, and none of them have changed.

    AJ >>

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