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Monroe sintered dollar mystery solved.

I just saw on the coin world website that maganese oxide was the culprit. I buy these issues from a coin store and he doesn't have the newest issue until friday. IF someone has an online subscription to coin world can you please cut and paste the full article here. I have some of these monroe sintered dollars and I'm curious as to what the article says. I've been wondering myself for months now what caused these dollars to be black as opposed to gold. These are fascinating coins if you see one in person. Some are extremely dark or almost a pitch black and some are just a light coating that really don't look that fascinating. When you put the really dark ones next to a normal monroe dollar it looks like the strike was done on a totally different metal.

Comments

  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭
    Well gosh.

    If this is really the case, I wonder why there aren't more blackened Wartime Nickels which had a much higher percentage of Manganese?

    Once again, Chris Pilliod throws his opinion into the ring.

    To me, it appears that he had his own theory regarding these and then set about to proving it.
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!
  • Please do not cut and paste the article here. Coin World articles are copyrighted and they have requested that they not be reproduced in the forums.

    Carol
  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭
    And for the OP, with CW's new setup, you don;t have a cut and paste option any more.
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!
  • notwilightnotwilight Posts: 12,864 ✭✭✭
    The brass that pres bucks are made of contains manganese. The problem occurrs when oxygen in introduced during annealing. --Jerry
  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭
    So why aren't blackened wartimes nickels more "abundant"?
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!
  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭


    << <i>The brass that pres bucks are made of contains manganese. The problem occurrs when oxygen in introduced during annealing. --Jerry >>



    Pilliod actually states that this could have occured at "any time" during the manufacturing process or under "typical environmental conditions". So the question arises, will, under "typical environmental conditions" a lot of Presidential and Sacajawea dollars begin to exhibit this condition?
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!
  • RWBRWB Posts: 8,082
    Oxide dust adhering to a planchet is not “sintering.”

    It didn’t happen with war nickels because the coins were a single alloy and annealing temperature was different.
  • So could someone give a summary of the article or pm me the article. Does the article conclude whether or not these are improperly annealed/sintering or some other type of terminology besides maganese oxide? Thanks
  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭


    << <i>Oxide dust adhering to a planchet is not “sintering.”

    It didn’t happen with war nickels because the coins were a single alloy and annealing temperature was different. >>



    Then, exactly what would sintering be Roger?

    Wouldn't the annealing temperature have been higher for the Silver Nickels or is Silver not as hard as copper?



    << <i>So could someone give a summary of the article or pm me the article. Does the article conclude whether or not these are improperly annealed/sintering or some other type of terminology besides maganese oxide? Thanks >>



    You'll have to wait on the article but it does not mention "sintering" or "improper annealing", only manganese oxide. How the TPG's will respond to this is unknown.
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!
  • Where else throughout the manufacturing process could the oxide dust adhere to the coin besides the annealing process?
  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭
    Pilliod is not saying an "oxide dust" but states "when it's (manganese) contents exceeds a certain level (indicating possible Improper Alloy Mix), it becomes prone to oxidation, and reacts with oxygen to form a surface contaminent."
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!
  • bronze6827bronze6827 Posts: 526 ✭✭✭
    Oxide dust adhering to a planchet is not “sintering.”
    It didn’t happen with war nickels because the coins were a single alloy and annealing temperature was different.

    This is all correct. I did not read the article, but several things here:
    1. Sintering is an actual bonding of materials on an atomic level
    2. War nickels were made of one homogeneous alloy, the vast percentage being silver. Not much experience with silver phase diagrams or silver heat treating, but I would presume the alloy does not readily oxidize at whatever the annealing temperature was, even if exposed to or annealed in atmosphere.
    3. What particular annealing process is used on the manganese brass dollars - as in what temperature, annealed in atmosphere, vacuum, or other inert gas? MUST know that information before making ANY determination of what questions to ask. Were the planchets removed from the furnace before they were below a certain temperature range? Were they done in vacuum and did the furnace have a leak and allow atmosphere to attack the planchets while at an eleveated temperature? Did the furnace run a cycle at too high a temperature? Did they get stuck in the annealing furnace and have over-extended cycle time? These are all very feasible possiblities. Many questions to answer here, and probably many more yet un-asked.
  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭
    Personally, I think the answer lies with the US Mint.

    For example, there have been thousands of Monroe dollars released which exhibit this darkening. However this is not limited to the Monroe coins as a few have been found with the Washingtons and the Adams coins as well.

    My guess is that something happened to create enough of these in one batch so that literally thousands of them could be found in a localized part of the country. This tells me that parhaps the QA Inspector at both the mint and the rolling facilities were "unavailable" because a quantity such as what has been reported would surely have caused them to be pulled. After all, its not like the average Joe COULDN'T pick these out from the rest of the crowd simply at a glance.

    Another thought could be that these are somehow linked to the Monroe coins tghat were minted on the quarter planchets.


    Nah................
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!
  • Llyds, I'm right here in Michigan where supposedly most of these were found and I did speak to alot of dealers about these and other finders of these coins. One dealer stated that he heard that a bank memo went around to certain areas in Michigan ordering the banks to return all Monroe boxes because of speculation that the so called monroe quarter planchets may have ended up there. A dealer I spoke to here in Michigan feels that it is possible that there never really was monroe dollars struck on quarter planchets, but instead these sintered or improperly annealed or whatever you call them were the real errors and whoever discovered them at the rolling company just assumed that they were quarters. Sounds far fetched, but i'm more inclined to think that this is really what happened as opposed to the monroe dollars being struck on quarter planchets.

    I do back you that the answer lies with the Mint. I don't know Chris Polliard or however you spell it, but I'm sure he does have a strong back ground in this field, but it would sure be nice to hear from the Mint about these coins and what their guess is. I found these myself and I heard of other experiences here in Michigan and from what I gathered these were found only at 2 banks and all finds were within about a 30 mile radius of downtown detroit, so these did indeed orginate from a certain batch and something did go wrong at a specific time for x amount of minutes or hours. In other words, and abberation did occur at one time as opposed to over and over again during different times and I believe the evidence of limited geographic areas backs this up. I don't have enough educational background on how the production process of coins works to speculate where or how this error occured, so I can't refute any arguments from Chris or anyone on this board, but once again I do knnow that the really dark coins I have are probably the neatest errors I have and I do have some leafs, smooth edges, clipped edges, and double lettering coins.
  • Well I called a coin shop that I frequently visit today and he said he should have the issue in by thursday, so maybe I will be able to gather a better understanding once I read the full article. What I'm trying to determine and what still isn't clear from the posts here does this scientific finding conclusively rule out that these were improperly annealed? The article headline basically says that the scientific tests done conclusively conclude that the discoloration was from the oxidation of the manganese and I guess what I'm trying to figure out is it more likely for the oxidation of manganese to occur in the annealing process than anywhere else? Would a more appropriate terminology be improperly mixed alloy as opposed to improperly annealed or maybe even improper chemical reaction planchet or just a straight manganese oxide planchet? Again, I don't have the chemistry background or the coin manufacturing process background that alot of you have on this board to understand this stuff. I have the monroe sintered dollars and I'm looking to buy one of each for the other presidents, however I would like to know what they are first before I start shelling out money for them.
  • I also have a few of these discolored monroe dollars and I've been wondering too what the real cause behind these is. I plan on sending some into pcgs, but I don't want to spend $40 a coin only to have them returned, so I'm going to wait until I send some other coins in next month and send one of my discolored monroe dollars in to see how they slab it before sending them more. I usually read coin world at the library each week and they don't get the new issues until saturday, so I guess I will have to wait to read it. Fred Weinberg seems to be the error guru on these boards so you might want to email him a picture of your coin or get his input on what he thinks of maganese oxide being the culprit. I believe he was quoted in the original article that came ot about a month ago. Most of the sintered coins I've been seeing on ebay have been labeled as improperly annealed or improper alloy mix and whether this will change now I have no idea.
  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭
    I have emailed Fred but he has not seen the article just yet. He does put a lot of trust in Pilliod though.

    As I stated, I can't help but wonder why this is coming up now asince these have been around since the Washington Dollars, just not in such large quantities. I'm in support of finding the truth but the general consensus has always been "sintered planchet". Fred even has some on his site.

    The TPG's will grade them as error's, but the first question will be, "What Kind of Error?". The second question will be "What do we do with those that are graded as sintered planchets?"

    image
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!


  • << <i>

    The TPG's will grade them as error's, but the first question will be, "What Kind of Error?". The second question will be "What do we do with those that are graded as sintered planchets?"

    image >>




    Llyds, I agree that they will still grade them as errors and as far as I'm concerned an error is an error regardless of the story behind it. Personally, I wouldn't mind seeing "manganese oxidation mint error" on the holders and to me this would sound even better than improperly annealed mint error or improper alloy mix. Either way these coins are really neat and for me I would much rather show these coins off in some kind of holder with a catchy name. Not only would this be neat to have, but also it would probably enhance the value when I sell any down the road.
  • 19Lyds19Lyds Posts: 26,492 ✭✭✭✭


    << <i>............... but also it would probably enhance the value when I sell any down the road. >>




    All except those thousands of Monroe's! image

    But, those could generate interest in the Washington's, which are not that common, and the Adams coins which again, are not that common.

    I'm actually kinda surprised that more of the Monroe's haven;t shown up on eBay! image
    I decided to change calling the bathroom the John and renamed it the Jim. I feel so much better saying I went to the Jim this morning.



    The name is LEE!

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