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Mystery 1942 one cent pattern? It has been analyzed using a Orbis Micro-XRF Elemental Analyzer - Ast

orevilleoreville Posts: 11,790 ✭✭✭✭✭
I am investigating this 1942 pattern. Andy Lustig gave it a shot and now it is my turn with Roger Burdette's help.

Photograph is by Todd of bluccphotos.

Yes, the question is what is the composition of this pattern. A sem-x test was already performed on this pattern coordinated by NGC and they could not figure it out. There appears to be some non metallic ingredients mixed in with metallic ingredients but that is conjecture at this point.

It does not appear to be a J-2054 or any other J-20XX out there. But I will have to take this to an advanced chemical laboratory to such to figure this out.

Any help is appreciated.

Edited.... see the results.


image
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    braddickbraddick Posts: 23,133 ✭✭✭✭✭
    Sort of related (I know you're asking about the example you posted exactly, but possibly for others...):

    1942 pattern LINK

    peacockcoins

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    CaptHenwayCaptHenway Posts: 31,564 ✭✭✭✭✭
    What is the question? Composition?
    Numismatist. 50 year member ANA. Winner of four ANA Heath Literary Awards; three Wayte and Olga Raymond Literary Awards; Numismatist of the Year Award 2009, and Lifetime Achievement Award 2020. Winner numerous NLG Literary Awards.
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    LanceNewmanOCCLanceNewmanOCC Posts: 19,999 ✭✭✭✭✭
    .
    don't the TPG offer metallurgic analysis for around $100?

    Maybe you could consult with a recommend private firm.

    the obv also resembles some centavo coins and some french coins maybe, others too.

    also it seems odd that it would say US Mint on the reverse for that time period. for all you pattern buffs you can determine this lettering style and layout based on other issues as one more bit of info.

    my knowledge of patterns is loose at best so i'm just throwing darts virtually blindly hoping at least one sticks.
    .

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    tahoe98tahoe98 Posts: 11,388 ✭✭✭


    << <i>What is the question? Composition? >>



    ...ditto image
    "government is not reason, it is not eloquence-it is a force! like fire, it is a dangerous servant and a fearful master; never for a moment should it be left to irresponsible action." George Washington
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    I'd ping Saul Teichman over at USPatterns as well (if you haven't already). Not sure if you have read this page or not either. Maybe grab a copy of that 9/42 Numismatist that is referenced? Good luck! I always enjoy when new info on a pattern is discovered.

    If it is metal, he recommends metallurgical analysis. Also listed is that they were also struck in plastic by Durez Plastics and Chemicals, the Patent Button Company, Blue Ridge Glass Corporation, Bakelite Corporation and Colt Patent Firearms Company.
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    CoinZipCoinZip Posts: 3,253 ✭✭✭



    Seems like an interesting research project.....good luck


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    LoveMyLibertyLoveMyLiberty Posts: 1,784 ✭✭✭

    The link DeliaBug listed is good information on this Experimental Composition Trial Piece.

    1942 ECTPiece, obv. Capped Liberty head right, adapted from a 1918 Colombia 2-centavos piece
    by John R. Sinnock. This head was used again in 1948 on a West German 20-mark note, Pick-9,
    printed by the U.S. Bur. of Engraving and Printing. Liberty at left border, Justice at right, date below.
    Rev. UNITED STATES MINT inside laurel wreath previously used on an 1860 $2.1/2, an 1863 3-cents,
    several U.S. Mint George Washington medals, Julian PR-25&26 and MT-22, and an Abraham Lincoln
    medal, Julian PR-36. Bronze. Plain Edge. Very rare.

    Same, zinc-coated steel. Plain Edge. Very rare. Stacks 9/90, lot 53, $2750; Stacks (ST) 3/92, lot 1591,
    MS $2100.

    Same, manganese. Plain Edge. Very rare

    Same, plastic various colors and textures. Plain Edge. Rare. Dark red, thick (approx. same as a proof
    Jefferson nickel), 0.65 gms and thin (approx. same as a Proof Lincoln cent) 0.38 gms; ST 3/92, MS $1200.
    Black (glossy surfaces but crumbling, fibrous edges) 0.35 gms. Bowers & Merena (BM) 1/92 sale: Black
    $1320; Brown $1100; Red brown $1100 ; Tan $231 and brass-colored $1100. Many exist broken to test
    durability. Typical specimen $1,000.

    Same, Bakelite, various colors. Plain Edge. Very rare. Red; ST 9/90 sale, lot 54, $1760; 3/92, lot 1592
    (same coin?) $1200 ; Green-Grey: ST 3/92, lot 1593, $600.

    Same, aluminum. Plain Edge. Very rare $1000.
    Pressed glass and other compositions reported. Some varying reports may refer to duplicate sightings of the
    same piece due to different interpretations of colors and compositions. Regular design 1942 cents in brass and
    zinc-coated steel reported, unconfirmed. Some may be on foreign planchets.

    This information was taken from "The Comprehensive Catalog and Encyclopedia of U.S. Coins", 2nd edition 1998,
    By the Editors Of Coin World.

    Should you have questions, or points of discussion regarding any of the above, please contact the Technical Editor
    Mr. Thomas K. DeLorey.
    image
    My Type Set

    R.I.P. Bear image
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    pcgs69pcgs69 Posts: 4,266 ✭✭✭✭
    I was flipping thru the nov 26th issue of coin world today and there was an article on similar/same design patterns. Didn't get a chance to read it though
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    Please see updated OP posting for additional clarification.
    A Collectors Universe poster since 1997!
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    CaptHenwayCaptHenway Posts: 31,564 ✭✭✭✭✭


    << <i>Please see updated OP posting for additional clarification. >>



    Thank you for that.

    What did the NGC test say, even if it was inconclusive?

    Numismatist. 50 year member ANA. Winner of four ANA Heath Literary Awards; three Wayte and Olga Raymond Literary Awards; Numismatist of the Year Award 2009, and Lifetime Achievement Award 2020. Winner numerous NLG Literary Awards.
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    NGC said:

    "Manganese?"
    A Collectors Universe poster since 1997!
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    Looks like plasticized (or rubberized) white metal. Manganese would be one possibility, likely has tin and or zinc as well.

    Looks somewhat similar to the finish on early medals which had paper-like backings.
    Specialist in Lincoln Cents, Toned Type, and Slab enthusiast.
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    wondercoinwondercoin Posts: 16,709 ✭✭✭✭✭
    In another year justin might be able to get it tested in his chemisty dept at ucla for you. Wondercoin.
    Please visit my website at www.wondercoins.com and my ebay auctions under my user name www.wondercoin.com.
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    keyman64keyman64 Posts: 15,456 ✭✭✭✭✭
    I don't think you should trouble yourself with it. Just send it to me. image
    "If it's not fun, it's not worth it." - KeyMan64
    Looking for Top Pop Mercury Dime Varieties & High Grade Mercury Dime Toners. :smile:
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    CaptHenwayCaptHenway Posts: 31,564 ✭✭✭✭✭
    Manganese is an interesting possibility. It was available, non-strategic, and apparently it does oxidize badly (which is why the warnix turn dark).

    Can you do a specific gravity on it?
    Numismatist. 50 year member ANA. Winner of four ANA Heath Literary Awards; three Wayte and Olga Raymond Literary Awards; Numismatist of the Year Award 2009, and Lifetime Achievement Award 2020. Winner numerous NLG Literary Awards.
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    If it's Manganese, then shouldn't it be a Judd 2055, Pollock 2075? Pollock similarly puts a question mark after the word Manganese. See page 390.

    I am curious about the whitish/yellow stuff in the date and elsewhere on the coin. I wonder if that whitish/yellow stuff is the source of the non-metallic contents of the SEM/EDX analysis.

    Can you provide more information from the SEM EDX analysis? Besides Manganese, specifically what else did the analysis show?
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    dcarrdcarr Posts: 8,017 ✭✭✭✭✭
    My first reaction, upon seeing the pictures, is that it is "Dow Metal".
    At least one of the listed so-called dollars is made of this alloy, which is mostly magnesium.


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    CaptHenwayCaptHenway Posts: 31,564 ✭✭✭✭✭
    Doesn't magnesium burst into flames when exposed to water?

    Could make doing a specific gravity test rather dangerous!
    Numismatist. 50 year member ANA. Winner of four ANA Heath Literary Awards; three Wayte and Olga Raymond Literary Awards; Numismatist of the Year Award 2009, and Lifetime Achievement Award 2020. Winner numerous NLG Literary Awards.
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    There's a big difference between Manganese, and Magnesium. They are two very different metals. This coin is an alloy of Manganese, not magnesium. In addition to Manganese, this coin might be an alloy that includes other elements, like iron, copper, or even silver. In addition, there is something on the surface of the coin that is probably causing the SEM-EDX analysis to show some non-metallic ingredients.

    I would still like to see more information from the SEM-EDX analysis that NGC performed.
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    tahoe98tahoe98 Posts: 11,388 ✭✭✭


    << <i>Manganese is an interesting possibility. It was available, non-strategic, and apparently it does oxidize badly (which is why the warnix turn dark).

    Can you do a specific gravity on it? >>




    ...oxidizing is one of the problems with the prez bucks too, because of the manganese. image (just an aside image)
    "government is not reason, it is not eloquence-it is a force! like fire, it is a dangerous servant and a fearful master; never for a moment should it be left to irresponsible action." George Washington
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    Thanks to one of our posters here, I have started to make arrangements hopefully in January 2013 for testing of this pattern at a testing facility that can perform various tests. I will list them shortly.

    (1)
    A Collectors Universe poster since 1997!
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    ranshdowranshdow Posts: 1,433 ✭✭✭✭
    Doesn't magnesium burst into flames when exposed to water?

    No. You may be thinking of sodium or potassium metal, which react violently with water.

    Magnesium, while reactive, doesn't react very easily in metal form on account of it develops a coating of oxide very quickly. Heat fine shavings to a high enough temperature however and they'll melt before bursting into a brilliant white flame. Mix magnesium powder with rust and you have the makings of Thermite, a tool for burning through steel. Ah, anyway.
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    FINALLY getting this pattern analyzed this weekend!
    A Collectors Universe poster since 1997!
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    Interesting thread. I was contacted to try to make some sense out of this coin and read through this thread and have the following comments. Some of these Judd Alloy descriptions seem a bit to general. Brass, bronze, zinc, zinc coated steel, manganese. Normally with brass we usually see some tin (bronze) in trace - Zinc and manganese by themselves? What are the other metals of the alloy? Aluminum alloyed with what else as the final alloy? Lead by itself? Maybe Pb & hardening elements like seen in Bryan Money? Confirmed (V.High Lead/with low Sn/Fe/Cu type alloy - for the typical soft metal vareity types that appear as Pb to the collector). Not sure what I can do for plastic types? We will use an EDAX-Orbis (www.edax.com) device that can analyze BOTH in vacuum (elements less than Sc on the Periodic Table) and in air for comparison purposes. Anyway from this J2079 1942 Lincoln Cent and these other J2051/P2073 crude metal description die family listing the suite of analysis is Al, Si, Fe,Ag,Mg,Cu,Sn,Mn,Zn,Cr,Pg,Sb & Sn. Al, Mg & Si requiring vacuum analysis. There was a response of SEM/EDS not sure what a microstructure analysis will give you as we are looking for a general overall composition although these brassy areas will need further evaluation as they appear to be some type of secondary coating or a form of improper alloy mixing as was reported recently by me in the Ted Cragie/Stacks Sale of Rosa's - lot #59? SEM/EDS is for detailed grain size/boundary area compositional analyses and outside this task. I may introduce Hg to confirm its not some form of amalgamated coating. Any comments before the analysis on Sunday? This piece does look challenging. REALLY DOES.

    Here is a full compositional analysis for a typical lead type Bryan Money specimen: Lead (97.12%), Tin (0.86%), Iron (0.23%), Copper (0.33%), Zinc (0.1%), Platinum (0.25%), Gold (0.28%) and Bismuth (0.35%). Note that Tin, Iron and Copper are introduced to harden the alloy and we see gold a common contaminat in lead ore processing and with gold we usually find its brother element platinum as seen in silver alloys. Bismuth also being a trace mining ore by-product.

    John Lorenzo
    Numsmatist
    United States
    Primarily a collector of error coins over the next decade after collecting for 40 years. Have collected & studied every coin series in the Western Hemishere - yes - even ...
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    This mystery 1942 pattern has finally been analyzed by John Lorenzo (colonialjohn) on an Orbis Micro-XRF Elemental Analyzer.

    The Orbis Micro-XRF Elemental Analyzer has improved sensitivity for heavier elements compared to SEM/EDS. It also functions within a non-destructive air or vacuum environment for better testing environment and/or control.

    John tested the obverse twice and the reverse twice in two different areas.

    He was very deliberate and very careful in his analysis.

    The results are astonishing!

    It was NOT what we expected at all.

    I will confirm the results with both John Lorenzo and Roger Burdette.







    A Collectors Universe poster since 1997!
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    CaptHenwayCaptHenway Posts: 31,564 ✭✭✭✭✭


    << <i>This mystery 1942 pattern has finally been analyzed by John Lorenzo on one of the most advanced machinery available in the world. and the results are astonishing!

    It was NOT what we expected at all.

    I will confirm the results with both John Lorenzo and Roger Burdette. >>



    Lemon curry?
    Numismatist. 50 year member ANA. Winner of four ANA Heath Literary Awards; three Wayte and Olga Raymond Literary Awards; Numismatist of the Year Award 2009, and Lifetime Achievement Award 2020. Winner numerous NLG Literary Awards.
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    We are still analyzing the results and will release them as soon as possible.

    No, no lemon curry.

    It is a metallic pattern but NOT made of zinc plated steel!

    A Collectors Universe poster since 1997!
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    coindeucecoindeuce Posts: 13,472 ✭✭✭✭✭
    Cheap grade of sintered steel?

    "Everything is on its way to somewhere. Everything." - George Malley, Phenomenon
    http://www.americanlegacycoins.com

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    keyman64keyman64 Posts: 15,456 ✭✭✭✭✭
    Congrats on getting results! I would not have guessed it to be mostly lead. Very interesting.
    "If it's not fun, it's not worth it." - KeyMan64
    Looking for Top Pop Mercury Dime Varieties & High Grade Mercury Dime Toners. :smile:
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    Not lead at all.
    A Collectors Universe poster since 1997!
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    keyman64keyman64 Posts: 15,456 ✭✭✭✭✭


    << <i>Not lead at all. >>

    Oh, I thought I read above that it is 97.12% lead...maybe I misread and that was another example. So what is this example?
    "If it's not fun, it's not worth it." - KeyMan64
    Looking for Top Pop Mercury Dime Varieties & High Grade Mercury Dime Toners. :smile:
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    LochNESSLochNESS Posts: 4,829 ✭✭✭


    << <i>Doesn't magnesium burst into flames when exposed to water?

    No. You may be thinking of sodium or potassium metal, which react violently with water.

    Magnesium, while reactive, doesn't react very easily in metal form on account of it develops a coating of oxide very quickly. Heat fine shavings to a high enough temperature however and they'll melt before bursting into a brilliant white flame. Mix magnesium powder with rust and you have the makings of Thermite, a tool for burning through steel. Ah, anyway. >>


    I backpack a lot, and magnesium sticks are common fire-starter "tools." They definitely don't react to water. You scrape the mag stick with your knife or other metal tool, and sparks jump out onto the kindling. image
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    TomBTomB Posts: 20,739 ✭✭✭✭✭
    Pure sodium and potasium metals result in a burst of flames when put into contact with water. It is a quite dramatic and highly energetic reaction.
    Thomas Bush Numismatics & Numismatic Photography

    In honor of the memory of Cpl. Michael E. Thompson

    image
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    We never did find out about this one. What was it?
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    morbidstevemorbidsteve Posts: 571 ✭✭✭
    Funny, I was just reading my Lincoln Cent book by Kevin Flynn, it's on page 15. I'm not sure of it's designation, but it's done by then Chief Engraver John Sinnock.

    Steve
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    Whoa, I thought I had already released the findings and posted it here!

    Strange!

    I will follow up.

    A Collectors Universe poster since 1997!
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    LakesammmanLakesammman Posts: 17,294 ✭✭✭✭✭
    I thought tax season made it too taxing to post?? image

    Thanks for the tease......
    "My friends who see my collection sometimes ask what something costs. I tell them and they are in awe at my stupidity." (Baccaruda, 12/03).I find it hard to believe that he (Trump) rushed to some hotel to meet girls of loose morals, although ours are undoubtedly the best in the world. (Putin 1/17) Gone but not forgotten. IGWT, Speedy, Bear, BigE, HokieFore, John Burns, Russ, TahoeDale, Dahlonega, Astrorat, Stewart Blay, Oldhoopster, Broadstruck, Ricko.
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    Per John Lorenzo:
    The 1942 Judd Pattern is of a predominant magnesium composition. We did confirm that it did not contain any manganese (J2055/P2075) and I mentioned to you the crude descriptions of these other Judd descriptions such as white metal, aluminum and lead? This appears unique as a Mg/Al/Si/Sb type alloy.

    For continuity we analyzed two XRF spots on the obverse and two XRF spots on the reverse to see the homogenous nature of the speciemn.

    Some results do not always equal 100% because sometime other minor constiuents may appear outside the targeted fingerprint list.

    The weight of the 1942 Judd Pattern is 2.5 grams and a diameter of 18.9 mm.

    The detailed results are shown in the next post.


    A Collectors Universe poster since 1997!
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    John Lorenzo tested the obverse and reverse two areas each for better confirmation.

    The findings are:

    Obverse.......................................Reverse

    Copper 0.40%/2.70%.................0.50%/0.43%
    Al 10.00%/9.80%.....................7.70%/10.37%
    Mg 71.30%/69.94%..................70.50%/70.44%
    Si 7.00%/6.50%........................7.50%/7.45%
    Sulfur 0.70%/ 0.66%...................0.75%/0.71%
    Sb 10.60%/ 10.40%....................11.33%/10.60%


    What is really interesting is that the Manganese metal used in the 1942-1945 war nickels is NOT seen in this pattern! Gosh I must be tired! I reverse the metals in my head!

    The next step is to bring some war nickels (one uncirculated and one circulated) as a control to compare them to this pattern to confirm this!



    A Collectors Universe poster since 1997!
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    illini420illini420 Posts: 11,466 ✭✭✭✭✭


    << <i>

    What is really interesting is that the predominant metal used in the 1942-1945 war nickels is possibly seen here as well.

    The next step is to bring some war nickels (one uncirculated and one circulated) as a control to compare them to this pattern. >>



    Not sure what you're saying here... the predominant metal in a war nickel is copper, right?? Followed by silver and manganese...

    There seems to be hardly any copper in your pattern and no silver or manganese.

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    dcarrdcarr Posts: 8,017 ✭✭✭✭✭


    << <i>... The results are astonishing! It was NOT what we expected at all. ... >>



    Not astonishing to me. In fact, it is what I expected image

    I said as much on the first page of this thread image :



    << <i>My first reaction, upon seeing the pictures, is that it is "Dow Metal".
    At least one of the listed so-called dollars is made of this alloy, which is mostly magnesium. >>

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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    I hope to test with more controls after April 15th.
    A Collectors Universe poster since 1997!
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    Cool, glad we finally found out about this one. I love these 1942 patterns.
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    orevilleoreville Posts: 11,790 ✭✭✭✭✭
    This Judd pattern at 2.5 grams (.08 troy oz) has the same weight as the current copper plated zinc in production since late 1982 and is fairly close to the zinc coated steel cents of 1943 which weighed 2.67 grams and about 20% lighter than the 3.11 grams bronze or brass cents minted between 1864 and 1982.


    Per Wikipedia:

    Years Material Mass (grams)
    1793–1796 100% copper 13.48
    1796–1857 100% copper 10.89
    1856–1864 88% copper, 12% nickel (also known as NS-12) 4.67
    1864–1942 "bronze" (95% copper, 5% tin and zinc) 3.11
    1943 zinc-coated steel (also known as 1943 steel cent) 2.67
    1944–1946 "brass" (95% copper, 5% zinc) 3.11
    1946–1962 "bronze" (95% copper, 5% tin and zinc)
    1962–1981 "brass" (95% copper, 5% zinc)
    1982 varies: "brass" (95% copper, 5% zinc) or copper-plated zinc (97.5% zinc, 2.5% copper)[7] 3.11 or 2.5
    1983–present 97.5% zinc, 2.5% copper (core: 99.2% zinc, 0.8% copper; plating: pure copper)[8] 2.5
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