Although they do not state it clearly on the benefits page, I have heard numerous times the set must be in the top CURRENT five, and of course be 100% complete. Sets with 10 or less items will only be pedigreed at PCGS's discretion.
They can pick what they want to do, too. The first set I had pedigreed was the fifth set in the top five and they would not qualify it. I was later able to move up a to fourth and get it pedigreed. Send them an e-mail with a link to your set and ask the question. The worst that can happen is they say no-not yet. Good luck.
President, Racine Numismatic Society 2013-2014; Variety Resource Dimes; See 6/8/12 CDN for my article on Winged Liberty Dimes; Ebay
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President, Racine Numismatic Society 2013-2014; Variety Resource Dimes; See 6/8/12 CDN for my article on Winged Liberty Dimes; Ebay