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A perfect example of how a high grade expensive proof can become a dog after it's holdered (large im

RussRuss Posts: 48,514 ✭✭✭
This coin is listed in the Heritage auction and is graded PR69DCAM:

image

image

Growing those ugly milk spots after removal from the proof set packaging is an all too common problem on these, and one that I've suffered myself. When the coin goes in for grading, it's pristine and beautiful. A few months to a year later, and it has grown ugly spots.

This is why I now give a quick light dip to every proof before submittal to remove any latent surface contaminants and stabilize the surfaces. None of those that have been stabilized first have ever developed spotting.

Russ, NCNE

Comments

  • BarryBarry Posts: 10,100 ✭✭✭
    Russ,
    What do you use for the dip?
  • RussRuss Posts: 48,514 ✭✭✭


    << <i>What do you use for the dip? >>



    eZest and neutralize with 99% isopropyl alcohol.

    Russ, NCNE
  • RYKRYK Posts: 35,797 ✭✭✭✭✭
    Yuck.

    That's one that PCGS should buy back (and redip and resell).
  • MyqqyMyqqy Posts: 9,777
    That's why it's reassuring to buy nice cams in older holders- at least you know the coin is relatively stable....
    My style is impetuous, my defense is impregnable !
  • RussRuss Posts: 48,514 ✭✭✭


    << <i>(and redip and resell). >>



    It wouldn't be a "re-dip". If it had been dipped before, the spots would not be there. Now it's too late. They will not come off with a dip.

    Russ, NCNE
  • RYKRYK Posts: 35,797 ✭✭✭✭✭
    They will not come off with a dip.

    I have no experience with this stuff. Is there any conservation technique to return this coin to its 69DCAM state? Or will the coin end up on DH's desk next to a 63 Lincoln cent?

    Agree with myqqy (fellow Steelers fan). It makes a good argument for buying older holder coins (modern and classic).
  • RussRuss Posts: 48,514 ✭✭✭


    << <i>Is there any conservation technique to return this coin to its 69DCAM state? >>



    There is none that I know of that will completely remove this type of problem, known as milk spotting. I've had some success with NCS reducing them, but even they seem unable to completely remove them.

    Russ, NCNE
  • LindeDadLindeDad Posts: 18,766 ✭✭✭✭✭
    Russ here is a side bar on this. That coin is really a low pop. How will it affect the value now that it's developing the milk spots. Or is it still going to sell at full value.
  • RussRuss Posts: 48,514 ✭✭✭


    << <i>How will it affect the value now that it's developing the milk spots. Or is it still going to sell at full value. >>



    Normal value range on these is $1200 to $1500. Last year, there was a spotted one listed on eBay and I said I thought it would bring around $800 or so. I wasn't even close. It brought over $1500.

    In the case of this coin, it's reserved at $2000. Unless some nut comes along, I don't think it will sell. BUT, the force has been strong in pop top early date proof Kennedys lately, so who knows?

    Russ, NCNE
  • RYKRYK Posts: 35,797 ✭✭✭✭✭
    Normal value range on these is $1200 to $1500. Last year, there was a spotted one listed on eBay and I said I thought it would bring around $800 or so. I wasn't even close. It brought over $1500.

    To what do you attribute this, Russ?

    Someone buying the holder, not the coin?
    Someone who is only concerned about registry standing?
    Someone who does not see/understand the spotting?

    Clearly, at the very best, the coin with spots is low-end for the grade.
  • LindeDadLindeDad Posts: 18,766 ✭✭✭✭✭
    Kind of what I thought. That registration number will check out as a PR69DCAM no matter what the coin looks like. To bad there isn't a way to protect your self morwe on them.
  • RussRuss Posts: 48,514 ✭✭✭


    << <i>Normal value range on these is $1200 to $1500. Last year, there was a spotted one listed on eBay and I said I thought it would bring around $800 or so. I wasn't even close. It brought over $1500.

    To what do you attribute this, Russ? >>



    Mercury rising in conjunction with Venus precipitating a state of cognitive dissonance in the bidders.

    Russ, NCNE
  • anablepanablep Posts: 5,097 ✭✭✭✭✭


    << <i>Mercury rising in conjunction with Venus precipitating a state of cognitive dissonance in the bidders. >>



    Hmmm...
    I'm lost.
    image
    Always looking for attractive rim toned Morgan and Peace dollars in PCGS or (older) ANA/ANACS holders!

    "Bongo hurtles along the rain soaked highway of life on underinflated bald retread tires."


    ~Wayne
  • If you all want another example check out this Lincoln:

    image
    image

    This coin used to be a PCGS PR 69 DCAM. I bought it sight unseen. Thankfully PCGS stood by their guarantee. This coin has the largest downgrade pointwise I've received.
  • keetskeets Posts: 25,351 ✭✭✭✭✭
    i don't think what you're seeing is milkspots, they don't develop over time since they are more accurately a strike through and not something that forms from contaminants on the coins surface. the stuff you're seeing---or that i'm seeing---is closer to haze or what can happen over time with water droplets from inadvertantly breathing/coughing on coins. it the same thing that's largely responsible for the problematic carbon spots on Lincolns.

    al h.image
  • RussRuss Posts: 48,514 ✭✭✭


    << <i>i don't think what you're seeing is milkspots, they don't develop over time >>



    They are, and they certainly do.

    Russ, NCNE
  • keetskeets Posts: 25,351 ✭✭✭✭✭
    whatever.

    al h.image
  • DHeathDHeath Posts: 8,472 ✭✭✭
    Robert,

    Your instinct is correct. Somebody might hurt themselves with that coin. Who knows why. Even though it's in plastic, it isn't invisible. Russ only put up one coin, but it's really not difficult to find tons listed that have turned in everyone's holder, sometimes due to a bad dip, and sometimes from natural causes. I suppose the grade guaranty affords some protection, but I'd only buy that coin if I stole it and intended on gambling with NCS.
    Developing theory is what we are meant to do as academic researchers
    and it sets us apart from practitioners and consultants. Gregor
  • JRoccoJRocco Posts: 14,277 ✭✭✭✭✭
    Hey Russ, Would there be any indication that these surfaces may have the likelihood of changing before the coin is removed from the original proof container? Is there some hint to look out for? And will the spotting remain dormant as long as the coin is still in its original container?
    Some coins are just plain "Interesting"
  • MyqqyMyqqy Posts: 9,777
    i don't think what you're seeing is milkspots,

    My understanding with franklins is that the spotting is probably the result of the washing formula the mint used on the plachets- I would think the same would hold true for 64 kennedys??

    This coin used to be a PCGS PR 69 DCAM. I bought it sight unseen. Thankfully PCGS stood by their guarantee. This coin has the largest downgrade pointwise I've received

    Carl- what was the grade given after it downgraded?
    My style is impetuous, my defense is impregnable !
  • keetskeets Posts: 25,351 ✭✭✭✭✭
    you understand correctly.

    al h.image
  • <Carl- what was the grade given after it downgraded? >

    That Lincoln is now a PR RD 65 DCAM. It is a shame as the cameo contrast is superb.

  • RussRuss Posts: 48,514 ✭✭✭


    << <i>Would there be any indication that these surfaces may have the likelihood of changing before the coin is removed from the original proof container? >>



    Unfortunately, no. Usually, if it's going to happen the milk-spotting has already developed while the coins are still in the packaging and it'll be obvious before you open the celo. But, there are some that look just fine and then after a period of time of being out of the packaging begin to develop the spots from the contaminants on the planchet (mint planchet rinse) that had laid dormant over the years.

    Here's another example:

    image

    That coin was spot-free PR67CAM when submitted. A year later, that's what it looked like. The spots are exactly of the type and nature frequently found on these before removal from the packaging. I really don't know or understand the underlying chemistry involved; I only know from personal experience that this happens.

    Russ, NCNE
  • ldhairldhair Posts: 7,232 ✭✭✭✭✭


    << <i>This is why I now give a quick light dip to every proof before submittal to remove any latent surface contaminants and stabilize the surfaces. None of those that have been stabilized first have ever developed spotting. >>


    My thoughts as well.image
    Larry

  • RussRuss Posts: 48,514 ✭✭✭
    Here's another example:

    image

    That coin was spot-free and graded PR67 when submitted. A few months later, that's what it looked like.

    Russ, NCNE
  • JRoccoJRocco Posts: 14,277 ✭✭✭✭✭
    Thanks for the answer Russ and that coin sure shows what your saying. If your not giving away any trade secrets- How quick do you dip the coin for? I ask this as a total virgin when it comes to dipping a coin, but after reading this thread, when the day comes and I look thru my truly unsearched proof sets, I may want to dip any keepers before sending them in for slabbing.
    Some coins are just plain "Interesting"
  • keetskeets Posts: 25,351 ✭✭✭✭✭
    hey Russ

    HRH mentioned this issue either at a luncheon or in a response to a question, either at the Q&A or when he used to drop in here from time to time. it's also been discussed along with the fingerprint issues. though the last coin may have been spot free when submitted, breathing on it would cause condensation or minute water droplets to be deposited on the surface. it might be the submitter and it might be someone at PCGS-----similar to the fingerprint issue. either way, it seems more logical for that to happen and cause the spotting than for a coin to have the possibility of forming Milk Spots from the residue of the Mint planchet rinse after 50+ years in a Mint Cello and only doing so when it's removed.

    al h.image
  • RussRuss Posts: 48,514 ✭✭✭


    << <i>If your not giving away any trade secrets- How quick do you dip the coin for? >>



    If all I'm doing is surface stabilization, no more than five seconds.

    Russ, NCNE
  • RussRuss Posts: 48,514 ✭✭✭


    << <i>HRH mentioned this issue either at a luncheon or in a response to a question, either at the Q&A or when he used to drop in here from time to time. it's also been discussed along with the fingerprint issues. though the last coin may have been spot free when submitted, breathing on it would cause condensation or minute water droplets to be deposited on the surface. it might be the submitter and it might be someone at PCGS-----similar to the fingerprint issue. either way, it seems more logical for that to happen and cause the spotting than for a coin to have the possibility of forming Milk Spots from the residue of the Mint planchet rinse after 50+ years in a Mint Cello and only doing so when it's removed. >>



    It may seem more logical, and it may actually happen. But, it has NEVER happened with any coin I've dipped in advance; only with coins that were not dipped. It has also happened with coins I set aside and never submitted. There is no question in my mind that the problem on the coins I posted is a result of latent contaminants from the mint.

    Russ, NCNE
  • tmot99tmot99 Posts: 5,238 ✭✭✭
    This "developing" of milk spots does not surprise me that it happens over time after it has been removed from the cello. This is very similar to a problem camera manufacturers had shipping cameras and lenses around the globe. They were clean when they left the factory, but when they were sold, white fingerprints had formed primarily on the lenses. As it turns out, fingerprints were left on the lenses. The superglue that was used to assemble the lenses reacted with the proteins and chemicals in the fingerprint and formed a hard white substance. This only happens under ideal conditions, typically a little warmth and humidity. After this discovery, they now develop fingerprints in crime labs this way. Anybody that's watched CSI has seen this.

    The reason that some develop in the cello and some after is due to the celo itself. A little bit of rub can create minute holes in the cello which can allow enough water vapor/humidity to enter into the package and turn the spots white (not saying this is the same reaction as the fingerprints). The ones that don't turn until after they are removed are probably in better packaging and the coin is not introduced to the environmental conditions to create the spots.

    For those who may think I am making any of this up, I worked in a crime lab for a couple of years early on in my career and now sell equipment that tests water vapor permeation through packaging materials like cellophane. For the record, I am not saying this is 100% sure this is why this happens sometimes and not others, but it does make a lot of sense.
  • keetskeets Posts: 25,351 ✭✭✭✭✭
    hey Russ and tmtot99

    milk spots are a strike through of the unremoved rinse residue and actually a part of the coins surface and can't be removed, i think we can agree on that, right?? i recall some members submitting coins to NCS with Milk Spots and the spots were minimized but not removed, leaving an easily visible "shadow" where the spot had been.

    i would suggest that the coins you claim to have dipped with no later ocurrence of spots never had them to begin with. they couldn't have been removed without leaving some evidence of having been there, unless you have a technique which is past what NCS knows about.

    al h.image


  • << <i>The superglue that was used to assemble the lenses reacted with the proteins and chemicals in the fingerprint and formed a hard white substance >>



    This makes me wonder if slabs are sealed with superglue. image
  • tmot99tmot99 Posts: 5,238 ✭✭✭
    Keets, I am not knowledgeable about the rince agent. I will take yours and Russ' word on that. My comments were that the rinse agent may be left on the coin, but it is not until it reacts with the environment outside the packaging that they turn white.

    With the fingerprint residue idea, the fingerprint can be removed if it hasn't reacted with the superglue, but once it has reacted, it becomes more difficult to remove. In fact, they frequently develop the prints with the superglue and then dust. They can do a couple of lifts of the fingerprint. Sometimes the later lifts are clearer than the first. If they didn't use the superglue, they would only get one maybe two lifts which is not as good.

    In the case of these coins, could it be possible that Russ' stabilization is rinsing the mint's rinse agent before it has time to react with the environmental conditions? Is it possible that NCS cannot remove the already reacted residue as it may be more stable as in the case of the fingerprints? These questions are not to be snotty or retorical. I have absolutely no experience with these spots.



    Edited in order to apply the English language.

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