Have your RED cents turned BROWN?

Have any of you had your certified RED cents turn BROWN while in their slabs?
What do you do if that happens? Because as I understand it, red cents are in general worth more than brown ones, for the same date and MM.
What do you do if that happens? Because as I understand it, red cents are in general worth more than brown ones, for the same date and MM.
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I know of someone that the experts consult on whether or not a slabbed coin is in danger of turning. I guess it's rare, but
it can happen. I would imagine from contaminants on the coin prior to slabbing. mdwoods
We'll use our hands and hearts and if we must we'll use our heads.
I have, unfortunately, seen numerous "RB" copper coins in "RD" holders and "BN" ones in "RB" holders, where the only plausible explanation is that the coins had "turned" in the holders. The price differences can be very large, in terms of both dollars and percentages.
It is my understanding that PCGS guarantees their copper coins (they reimbursed us a fair market value difference in price, for a "RD" example that had changed to "RB"). NGC recently began guaranteeing their copper, as well, subject to it already being in, or screened and approved for encapsulation in, their new holders.
And the point is????
Why do copper coins turn brown when they oxidize (oops, I mean tone), and not green like cooper a copper roof?
As I recall from college chemistry, a long time ago, copper is multi-valent (is that the right word?) and can combine in the cuprous or cupric form. I presume it has something to do with that. Can anyone explain in some detail?
I've seen many RB coins in red holders but have never been sure if these were properly graded in the first place. Some dates tend to get the benifit of the doubt and those years have alot of RB coins in red holders. I bought one of these recently, a 1867, just because I loved the toning and strike.
Anyway, I would love to hear from anyone that has a bonafide story regarding a ORIGINAL red PCGS coin turning RB while they owned it. I'm sure it's happened but it's gotta be for a reason (AT to begin with, improper storage, etc).
Stewart - what's your experience??
<< <i>I wasn't aware that slabs were 100% air tight. If they are, then I suppose copper would remain as sealed >>
topstuff, supposedly, gases can permeate the plastic and the oxidation process, which begins before a coin is sealed, can continue afterwards, regardless of the holder. I strongly recommend that people be "anally compulsive" about storage, like Lakesammman is.
Here's a warning parable for coin collectors...
Edited to add: Sorry, deleted due to technical difficulties.
I was just having fun with Shylock.
Edited to add: Sorry, deleted due to technical difficulties.
Heritage's red IHCs frequently look RB. It's just a function of their imaging skills. That 79 sure does look awful.
Tom
Check out some of my 1794 Large Cents on www.coingallery.org
<< <i>Rick Snow has said that he has not seen any red copper indian cents that was properly graded turn brown in a holder. He says that if it has not turned in the past 100 years, what makes you think that it will turn while you have it >>
I must strongly disagree with that comment. But, I do agree with your mention of the changed environment, Tom.
A "RD" copper coin (or any other coin, for that matter) might remain undisturbed for decades and then, in a short time span, be subjected to a changed/different environment, as well as handling by a number of people. The fact that a "RD"coin has defied the odds and remained "RD" for many years, does not mean it will continue to do so, especially, once it's environment has changed.
The surprise should not be that a "RD" coin turns to "RB", but rather, that it remained "RD" for as long as it did.
David
A couple of weeks back I saw a nice newly encapsulated MS65RD IHC in an online dealer's inventory. I thought it would fit in well with my collection until I heard its history.
Turns out it was bought raw from a Stack's auction about six months ago. The day the new owner took it home it just happened to be a chilly -10 degrees in NYC. That in itself wouldn't have been so bad, but it was really snowing and the ground was extremely icy. They had just thrown some salt down, but it really wasn't too effective yet. Unfortunately, the owner fell hard to the ground dropping the coin in a salty, slushy mess. He sure hoped the envelope had protected it.
When he arrived at his apartment with the coin he was relieved that the coin looked fine. He left it to dry out near the fireplace and went next door to the Chinese restaurant to grab something to eat.
The next day it was off to be graded.
Unfortunately the weather was damn hot in SoCal. The postal truck had poor air circulation and the small package had become lodged under a seat. It spent three days and three nights out in the blistering heat in the truck. More unfortunately, the post office parking lot was located near a strong ammonia smelling pesticide factory. But after those three days it was found and subsequently arrived at its destination.
Three months later, the day it was in the grading room was a miserable one. Everyone had some mysterious flulike illness, with the accompanying hacking, wheezing, and expectorating. It was nearly impossible to keep a few droplets from falling on the coin. Involuntary bodily movements made it very difficult to hold the coin firmly on its edge and one or two thumbs surely grazed its surface.
A month later the coin was back in NYC and looked really fine in its new slab. The owner was pleased with the grade, but decided to consign it with the well known dealer.
I really like the look of this coin and it is a date that I need, but I am concerned its appearance could change for the worst over time. Should I be worried?
After 30+ years in my care they were nice red coins.
Something to do with the poly bags, the flips, the trip to PCGS
or something else turned several to RB after a couple of years.
Kinda sad.
Anyway, before I was familar with the PCGS guarantee.
few years ago, While I was visiting in Idaho, (Cool dry, low humidity) I purchased a beautiful full red 1914-d PCGS-64 RD Lincoln cent. After bringing it back to North Carolina (high humidity), and after several months I began to notice a slight browning effect, it got to the point where it looked RB to me. To this day, I believe that the enviroment change from Idaho to North carolina created the change in color.
Several of the experienced copper members on this board indicated it was probably just me, maybe it was, but I am still not convinced!
Mark - Lakesamman may be anally compulsive but you are certainly anally retentive.I luv ya Mark
Why a coin could change color?
1) composition of metal mixture - wood grain toning
2) PCGS slabs are not air tite
3) NGC (new) slabs are air tite
a)if a coin is left for a period in the sun..it WILL tone
Copper has been dippedsince at least the 1950's,
and has taken a pink hue.Some is market acceptable and others get body bagged.Some mechanics are better than others.
After a coin is dipped it must be washed with water thoroughly and some techniques work better than others.Every coin mechanic screws up coins.Sometimes they get lucky but they will always screw up some coins.
Acetone - is used to get glue,goo and schmutz off a coin.It is also used to enhance luster
ms 70 - Will cause copper to turn the color of Russ's 1882 Indian cent in the ms 63 Brown holder.It is a magenta or purplish color
For the above reasons a copper coin can change color in the holder.I own a full red 1807 Large cent that is graded ms 66 red by PCGS.This coin managed to stay red for 200 years.
I also believe that luck is an unexplainable factor
stewart
Copper coin conservation
and it sets us apart from practitioners and consultants. Gregor
They look OK.
K S
Yikes Karl, you may have started mass destruction of plastic slabs.
Imagine all the slabbed coins hidden in attics in Florida, just leaching away and turning coins ??? Hope somebody offers a reason that counters your claim, before everyone runs out to buy a claw hammer.